Published December 1, 1986
| Published
Journal Article
Open
Resonance effects in the 5σ photoionization of CO
- Creators
- Smith, Maile E.
- Lynch, Diane L.
- McKoy, Vincent
Chicago
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Abstract
We report vibrational branching ratios and vibrationally resolved photoelectron angular distributions for resonant photoionization of the 5sigma level of CO leading to X^2Σ+CO+. These results were obtained using frozen-core Hartree–Fock photoelectron continuum orbitals. These studies provide a clear quantitative picture of the role of the kσ shape resonance in the observed non-Franck–Condon behavior and useful insight into the interplay between this shape resonance and a valence-like autoionizing resonance around 23 eV.
Additional Information
Copyright © 1986 American Institute of Physics. Received 18 August 1986; accepted 27 August 1986. This material is based on research supported by the National Science Foundation under Grant No. CHE-8521391. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 7435.Attached Files
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Additional details
- Eprint ID
- 11687
- Resolver ID
- CaltechAUTHORS:SMIjcp86
- National Science Foundation
- CHE-8521391
- Created
-
2008-09-18Created from EPrint's datestamp field
- Updated
-
2021-11-08Created from EPrint's last_modified field
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7435