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Published December 1, 1986 | Published
Journal Article Open

Resonance effects in the 5σ photoionization of CO

Abstract

We report vibrational branching ratios and vibrationally resolved photoelectron angular distributions for resonant photoionization of the 5sigma level of CO leading to X^2Σ+CO+. These results were obtained using frozen-core Hartree–Fock photoelectron continuum orbitals. These studies provide a clear quantitative picture of the role of the kσ shape resonance in the observed non-Franck–Condon behavior and useful insight into the interplay between this shape resonance and a valence-like autoionizing resonance around 23 eV.

Additional Information

Copyright © 1986 American Institute of Physics. Received 18 August 1986; accepted 27 August 1986. This material is based on research supported by the National Science Foundation under Grant No. CHE-8521391. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 7435.

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