Published July 1, 1982
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Journal Article
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Ab initio study of vibrational excitation of HF by low-energy electrons
Chicago
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Abstract
Fixed-nuclei, static-exchange calculations have been performed to study the vibrational-rotational excitation of HF by electrons from threshold to 5 eV. Our calculated, R-dependent K-matrix elements in 2Σ+, 2Π, and 2Δ symmetry are combined with exact point-dipole and laboratory-frame first-Born-approximation results for higher symmetries to obtain converged, integrated cross sections. The calculations show strong threshold peaks which are related to the dependence of the 2Σ+ K-matrix elements on internuclear distance at small scattering energies.
Additional Information
© 1982 by The American Physical Society. Received 25 January 1982. This work was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under Contract No. W-7405-ENG-48. B.V.M. acknowledges the support of the NSF under Grant No. CHE 80-40870.Files
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