Published November 24, 2008
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Journal Article
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Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes
Abstract
Palladium complexes supported by tridentate phosphido diphosphine ligands (P(o-C6H4PR2)2: 1, R = iPr; 2, R = Ph) have been synthesized, characterized, and tested as catalysts for the electrophilic allylation of aldehydes. The palladium complex 2 resulted in an interesting catalyst for electrophilic allylation in the presence of allyltributyltin, giving good yields under very mild reaction conditions and even in the absence of the solvent.
Additional Information
Copyright © 2008 American Chemical Society. Received September 3, 2008. Publication Date (Web): October 22, 2008. We thank Matt T. Whited for assistance with crystallographic studies. Supporting Information: Text, figures, and tables giving experimental procedures for the synthesis and characterization data of compounds 1 and 2 and X-ray structural solution and crystal data for 1; X-ray data for 1 are also given as a CIF file. This material is available free of charge via the Internet at http://pubs.acs.org.Attached Files
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Additional details
- Eprint ID
- 12675
- Resolver ID
- CaltechAUTHORS:MAZo08
- Created
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2008-12-19Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field