Published 1973
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Journal Article
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Central-field intermolecular potentials from the differential elastic scattering of H2(D2) by other molecules
Chicago
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Abstract
Differential elastic scattering cross sections for the systems H2+ O2, SF6, NH3, CO, and CH4 and for D2+ O2, SF6, and NH3 have been obtained from crossed beam studies. In all cases, rapid quantum oscillations have been resolved which permit the determination of intermolecular potential parameters if a central-field assumption is adopted. These potentials were found to be independent of both the isotopic form of the hydrogen molecule, and the relative collision energy. As a result of this, and the ability of these spherical potentials quantitatively to describe the measured scattering, it is concluded that anisotropy effects do not seem to be important in these H2(D2) systems.
Additional Information
© Royal Society of Chemistry 1973 Received 26th February, 1973 Work supported in part by the U.S. Atomic Energy Commission, Report Code No. CALT-767P4-112 Work performed in partial fulfilment of the requirements for the Ph.D. Degree in Chemistry [M.J.C.] at the California Institute of Technology. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 4650.Files
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- Eprint ID
- 4789
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- CaltechAUTHORS:KUPfdcs73
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