Published March 8, 2005
| Published
Journal Article
Open
Long-range electron transfer
- Creators
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Gray, Harry B.
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Winkler, Jay R.
Chicago
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Abstract
Recent investigations have shed much light on the nuclear and electronic factors that control the rates of long-range electron tunneling through molecules in aqueous and organic glasses as well as through bonds in donor-bridge-acceptor complexes. Couplings through covalent and hydrogen bonds are much stronger than those across van der Waals gaps, and these differences in coupling between bonded and nonbonded atoms account for the dependence of tunneling rates on the structure of the media between redox sites in Ru-modified proteins and protein-protein complexes.
Additional Information
© 2005 by the National Academy of Sciences. Edited by Jack Halpern, University of Chicago, Chicago, IL and accepted January 28, 2005 (received for review January 5, 2005). Our work is supported by the National Institutes of Health, the National Science Foundation, BP, and the Arnold and Mabel Beckman Foundation. This paper was submitted directly (Track II) to the PNAS office.Attached Files
Published - GRApnas05b.pdf
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Additional details
- PMCID
- PMC553296
- Eprint ID
- 952
- Resolver ID
- CaltechAUTHORS:GRApnas05b
- NIH
- NSF
- BP
- Arnold and Mabel Beckman Foundation
- Created
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2005-11-15Created from EPrint's datestamp field
- Updated
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2023-06-01Created from EPrint's last_modified field