Published May 5, 1967
| Published
Journal Article
Open
Improved quantum theory of many-electron systems. I. Construction of eigenfunctions of Ŝ^2 which satisfy Pauli's principle
- Creators
-
Goddard, William A., III
Abstract
A general method of obtaining many-electron wave functions which are eigenfunctions of S-^2 and which also satisfy Pauli's principle is developed. This method is based on the properties of the irreducible units of the group algebra of the symmetric group. Using this method, expansions of the exact wave function are found which will in succeeding articles form the basis of a powerful method of obtaining accurate and quite useful many-electron wave functions for atoms, molecules, and solids.
Additional Information
©1967 The American Physical Society. Received 15 December 1965; revised 30 September 1966. We wish to express our sincere appreciation to Professor Sunney I. Chan and to Dr. Russell M. Pitzer for their helpful discussions and instructive criticisms of the manuscript, to Professor Pol Duwez for encouragement, and to Dr. Paul Pietrokowsky for inspiration.Attached Files
Published - WAG-0001-GODDpr67a.pdf
Files
WAG-0001-GODDpr67a.pdf
Files
(1.3 MB)
| Name | Size | Download all |
|---|---|---|
|
md5:2c920c9853ff16f15c8d92768db1e2cf
|
1.3 MB | Preview Download |
Additional details
- Eprint ID
- 3117
- Resolver ID
- CaltechAUTHORS:GODDpr67a
- Created
-
2006-05-16Created from EPrint's datestamp field
- Updated
-
2021-11-08Created from EPrint's last_modified field
- Other Numbering System Name
- WAG
- Other Numbering System Identifier
- 0001