Published November 10, 2008
| Accepted Version
Journal Article
Open
Ping-Pong Electron Transfer through DNA
Abstract
Herein we describe a novel Ir system that is able to promote the reduction of pyrimidine bases from a distance without the presence of an external quencher. Instead, DNA-mediated ET is triggered by DNA-mediated HT. Thus, photoactivation of these Ir assemblies results in both a forward and a reverse pattern for charge migration, which we term ping-pong electron transfer through DNA (Scheme 1).
Additional Information
© 2008 Wiley-VCH. Received: July 22, 2008. Published online: October 16, 2008. This work was supported by the NIH (GM49216).Attached Files
Accepted Version - nihms106735.pdf
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nihms106735.pdf
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Additional details
- PMCID
- PMC2748353
- Eprint ID
- 12565
- Resolver ID
- CaltechAUTHORS:ELIac08
- NIH
- GM49216
- Created
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2008-12-12Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field