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Published April 1, 1968 | public
Journal Article Open

Quantum-Mechanical Treatment of Inelastic Collisions. II. Exchange Reactions

Abstract

The theory for the quantum-mechanical treatment of inelastic collisions developed in the first paper of this series is extended to treat collinear, electronically adiabatic exchange reactions. The formalism is applied to three model potential energy surfaces for the exchange of identical particles. The calculated reaction probabilities are reasonable and two independent checks indicate that they are reliable.

Additional Information

Copyright © 1968 American Institute of Physics. Received 27 October 1967. [D.J.D. was an] NSF Predoctoral Fellow 1964-1967. This paper is based on part of the thesis of DJD submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the California Institute of Technology. Gates and Crellin Laboratories of Chemistry, Contribution No. 3590.

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August 21, 2023
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