Published August 1, 2000
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Journal Article
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Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin
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Abstract
Dicobalt(II) cofacial bisporphyrins anchored by dibenzofuran (DPD) and xanthene (DPX) are efficient electrocatalysts for the four-electron reduction of oxygen to water despite their ca. 4 Å difference in metal–metal distances, suggesting that the considerable longitudinal Pac-Man flexibility of the pillared platforms is the origin for the similar catalytic reactivity of these structurally disparate systems.
Additional Information
© The Royal Society of Chemistry 2000. Received (in Bloomington, IN, USA) 16th February 2000; accepted 11th April 2000. Published on the Web 5th July 2000. C. J. C. gratefully acknowledges the National Science Foundation for a predoctoral fellowship. We thank A. Heyduk for help with the X-ray crystallography. This work was supported by the National Institutes of Health GM 47274.Attached Files
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Additional details
- Eprint ID
- 3790
- Resolver ID
- CaltechAUTHORS:CHAcc00
- NSF Predoctoral Fellowship
- NIH
- GM 47274
- Created
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2006-07-11Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field