Published February 22, 1993 | Published
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Vibrational entropy of ordered and disordered Ni3Al

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Abstract

We have measured the difference in vibrational entropy of Ni3Al in two states of chemical order: as a disordered fcc solid solution, and as the equilibrium L12 ordered structure. Data were obtained from three independent methods: low-temperature calorimetry, temperature-dependent x-ray diffractometry, and temperature-dependent extended electron energy loss fine structure spectrometry. We estimate that at high temperatures, the vibrational entropy of chemically disordered Ni3Al is 0.3kB/atom greater than for ordered Ni3Al.

Additional Information

© 1993 The American Physical Society Received 3 December 1992 This work was supported by the U.S. Department of Energy under Contract No. DE-FG03-86ER45270.

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