Published March 21, 2008
| Published + Supplemental Material + Cover Image
Journal Article
Open
Sulfur isotope fractionation during incorporation of sulfur nucleophiles into organic compounds
Abstract
34S enrichment is shown to occur during sulfurization reactions and for the first time conclusively attributed to an isotope equilibrium effect rather than selective addition of 34S enriched nucleophiles.
Additional Information
© Royal Society of Chemistry 2008. Received (in Cambridge, UK) 5th November 2007, Accepted 2nd January 2008. First published as an Advance Article on the web 16th January 2008. The authors wish to thank David Sprinzak (Caltech) for help with MATLAB programing and Alex Sessions (Caltech) and Dmitri Gelman (Hebrew University) for helpful comments and discussions on an earlier version of this paper. Electronic supplementary information (ESI) available: Experimental and molecular modeling procedures, optimized coordinates for all structures, supplementary data for Tables 1–3, GC-MS trace for some of the products. See DOI: 10.1039/b717113gAttached Files
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Additional details
- Eprint ID
- 10101
- Resolver ID
- CaltechAUTHORS:AMRcc08
- Created
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2008-04-14Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field