Published January 1978
| public
Journal Article
Mechanistic implications of the stereochemistry of singlet oxygen-olefin reactions
Abstract
We analyze the stereoselectivity of singlet oxygen-olefin reactions, concluding that a biradical peroxyl intermediate is involved and that experimental results are inconsistent with perepoxide intermediates.
Additional Information
© 1978 Published by Elsevier. We would like to thank Professor M. J. S. Dewar for bringing to our attention the results of Conia et al. This investigation was supported in part by the National Institutes of Health (Research Grant No. GM-23971) from the National Institute of General Medical Sciences. Acknowledgement is made to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. Computing assistance was obtained from the Health Sciences Computing Facility of the University of California, Los Angeles, supported by the National Institutes of Health, Research Resources Grant RR-3.Additional details
- Eprint ID
- 121750
- Resolver ID
- CaltechAUTHORS:20230607-256268000.2
- GM-23971
- NIH
- American Chemical Society Petroleum Research Fund
- RR-3
- NIH
- Created
-
2023-06-07Created from EPrint's datestamp field
- Updated
-
2023-06-07Created from EPrint's last_modified field
- Other Numbering System Name
- WAG
- Other Numbering System Identifier
- 0114