Published July 28, 2022
| public
Journal Article
Comment on "Liquid–Gas Interface of Iron Aqueous Solutions and Fenton Reagents"
- Creators
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Colussi, Agustín J.
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Enami, Shinichi
Chicago
An error occurred while generating the citation.
Abstract
A recent Letter in this Journal (Gladich et al. J. Phys. Chem. Lett. 13, 2994–3001) reported that photoelectron spectroscopy could not detect any products on the surface of aqueous Fe²⁺ jets dosed with gaseous hydrogen peroxide. The Letter however concluded that Fe(aq)²⁺ ions react with H₂O₂(g) at the water–vapor interface to produce the same Fe³⁺ + HO• products as their reaction with H₂O₂(aq) in bulk water. We argue that this conclusion is untenable because nothing can be asserted about undetected species.
Additional Information
© 2022 American Chemical Society. Received 6 April 2022. Accepted 13 July 2022. Published online 18 July 2022. The authors declare no competing financial interest.Additional details
- Eprint ID
- 115698
- DOI
- 10.1021/acs.jpclett.2c01006
- Resolver ID
- CaltechAUTHORS:20220720-917485000
- Created
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2022-07-22Created from EPrint's datestamp field
- Updated
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2022-08-15Created from EPrint's last_modified field