Published April 14, 2022
| Supplemental Material
Journal Article
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Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer
Abstract
The reaction of a Mo(ii) terminal nitride with U(iii) generates the first example of a transition metal capped uranium nitride. The nitride is triply bonded to U(v) and singly bonded to Mo(0) with a U–Mo interaction and reacts with CO to yield cyanate.
Additional Information
© The Royal Society of Chemistry 2022. Submitted 24 Jan 2022. Accepted 10 Mar 2022. First published 10 Mar 2022. M. M. acknowledges financial support from the Swiss National Science Foundation (grant 178793) and the Ecole Polytechnique Fédérale de Lausanne (EPFL) and thanks Dr A. Sienkiewicz for preliminary EPR data collection. T. A. is grateful to the NSF for financial support (CHE-1800501). L. M. is a senior member of the Institut Universitaire de France. CalMip is acknowledged for a generous grant of computing time. There are no conflicts to declare.Attached Files
Supplemental Material - d2cc00473a1.pdf
Supplemental Material - d2cc00473a2.cif
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Additional details
- Eprint ID
- 114023
- Resolver ID
- CaltechAUTHORS:20220323-704268000
- 178793
- Swiss National Science Foundation (SNSF)
- Ecole Polytechnique Fédérale de Lausanne (EPFL)
- CHE-1800501
- NSF
- Created
-
2022-03-23Created from EPrint's datestamp field
- Updated
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2022-04-08Created from EPrint's last_modified field