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Published March 10, 2022 | Supplemental Material
Journal Article Open

Weak cubic CaSiO₃ perovskite in the Earth's mantle

Abstract

Cubic CaSiO₃ perovskite is a major phase in subducted oceanic crust, where it forms at a depth of about 550 kilometres from majoritic garnet. However, its rheological properties at temperatures and pressures typical of the lower mantle are poorly known. Here we measured the plastic strength of cubic CaSiO₃ perovskite at pressure and temperature conditions typical for a subducting slab up to a depth of about 1,200 kilometres. In contrast to tetragonal CaSiO₃, previously investigated at room temperature, we find that cubic CaSiO₃ perovskite is a comparably weak phase at the temperatures of the lower mantle. We find that its strength and viscosity are substantially lower than that of bridgmanite and ferropericlase, possibly making cubic CaSiO₃ perovskite the weakest lower-mantle phase. Our findings suggest that cubic CaSiO₃ perovskite governs the dynamics of subducting slabs. Weak CaSiO₃ perovskite further provides a mechanism to separate subducted oceanic crust from the underlying mantle. Depending on the depth of the separation, basaltic crust could accumulate at the boundary between the upper and lower mantle, where cubic CaSiO₃ perovskite may contribute to the seismically observed regions of low shear-wave velocities in the uppermost lower mantle, or sink to the core–mantle boundary and explain the seismic anomalies associated with large low-shear-velocity provinces beneath Africa and the Pacific.

Additional Information

© 2022 Nature Publishing Group. Received 04 February 2021; Accepted 22 December 2021; Published 09 March 2022. We acknowledge technical assistance by A. Ehnes and I. Schwark. We thank A. R. Thomson for providing a table with the high-temperature shear modulus of CaSiO₃ perovskite. This research was supported through the German Science Foundation (grants MA4534/3-1 and MA4534/4-1) as well the European Union's Horizon 2020 research and innovation programme (ERC grant 864877). H.M. acknowledges support from the Bavarian Academy of Sciences. L..M acknowledges support from the NSF (EAR-1654687) and US Department of Energy National Nuclear Security Administration through the Chicago-DOE Alliance Center (DE-NA0003975). Data availability: Raw data were generated at the Deutsches Elektronen-Synchrotron (DESY) and are available at https://doi.org/10.6084/m9.figshare.17287361. All derived data supporting the findings of this study are available within the article and the Extended Data. Source data for Figs. 2, 3 and Extended Data Fig. 2 are provided with the paper. Contributions: H.M., H.-P.L., L.M. and S.S. designed the research. J.I. prepared the experiments. All authors contributed to the synchrotron experiments. J.I. and L.M. analysed the data. H.M. performed the modelling. H.M. wrote the initial draft of the manuscript. All authors contributed to the final writing of the manuscript. The authors declare no competing interest. Peer review information: Nature thanks Patrick Cordier and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.

Attached Files

Supplemental Material - 41586_2021_4378_Fig4_ESM.webp

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Supplemental Material - 41586_2021_4378_MOESM1_ESM.xlsx

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Supplemental Material - 41586_2021_4378_Tab1_ESM.jpg

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Created:
August 22, 2023
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