Discovery of davemaoite, CaSiO₃-perovskite, as a mineral from the lower mantle
Abstract
Calcium silicate perovskite, CaSiO₃, is arguably the most geochemically important phase in the lower mantle, because it concentrates elements that are incompatible in the upper mantle, including the heat-generating elements thorium and uranium, which have half-lives longer than the geologic history of Earth. We report CaSiO₃-perovskite as an approved mineral (IMA2020-012a) with the name davemaoite. The natural specimen of davemaoite proves the existence of compositional heterogeneity within the lower mantle. Our observations indicate that davemaoite also hosts potassium in addition to uranium and thorium in its structure. Hence, the regional and global abundances of davemaoite influence the heat budget of the deep mantle, where the mineral is thermodynamically stable.
Additional Information
© 2021 American Association for the Advancement of Science. Received 9 August 2021; accepted 21 September 2021. We thank N. Tomioka and an anonymous reviewer for their helpful comments. Funding: This work was supported by awards NSF-EAR-1838330, -EAR-1942042, and -EAR-1322082; the NSF Cooperative Agreement No. DMR-1644779; and the State of Florida. Use of the Advanced Photon Source and the Advanced Light Source were supported by the US Department of Energy, Basic Energy Sciences, contracts DE-AC02-06CH11357 and DE-AC02-05CH11231, respectively. Author contributions: O.T., S.H., S.Y., and M.H. participated in design, interpretation, data collection, and analysis of the reported results and in drafting and revising the manuscript. W.L., S.N.G.C., H.A.B., J.T., and G.R.R. participated in data collection and revising the manuscript. Competing interests: The authors have no competing interests. Data and materials availability: Additional chemical and crystallographic information about davemaoite is provided in the supplementary materials. Raw data are deposited at Dryad (23). Crystallographic and chemical information on type davemaoite is deposited in the Inorganic Crystal Structure Database. The type material is deposited with the NHMLA under accession number 74541.Attached Files
Supplemental Material - science.abl8568_data_s1.zip
Supplemental Material - science.abl8568_sm.pdf
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Additional details
- Alternative title
- Discovery of davemaoite, CaSiO3-perovskite, as a mineral from the lower mantle
- Eprint ID
- 111849
- DOI
- 10.1126/science.abl8568
- Resolver ID
- CaltechAUTHORS:20211111-221313042
- NSF
- EAR-1838330
- NSF
- EAR-1942042
- NSF
- EAR-1322082
- NSF
- DMR-1644779
- State of Florida
- Department of Energy (DOE)
- DE-AC02-06CH11357
- Department of Energy (DOE)
- DE-AC02-05CH11231
- Created
-
2021-11-11Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field
- Caltech groups
- Division of Geological and Planetary Sciences (GPS)