Published October 14, 2021
| Supplemental Material + Submitted
Journal Article
Open
Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex
Abstract
A neutral trialuminum complex incorporates a pentacoordinate carbon through a methylidene bridge linking the three metal atoms. The rigid electron-deficient Al3 core stabilizes the hypercoordinate carbon atom resulting in the shortest equatorial Al–C distance reported for such Al₃-(µ³-CH₂) unit.
Additional Information
© The Royal Society of Chemistry 2021. Submitted 05 Aug 2021; Accepted 01 Sep 2021; First published 01 Sep 2021. This work was supported by FONDECYT, Project No. 1200748. N. V. E. acknowledges financial support from Fondecyt-ANID Postdoctorado Grant 3210532. J. M. acknowledges financial support from Fondecyt-ANID Postdoctorado project 3180073. R. A. M. acknowledges financial support from FONDECYT Grant 1181260. Powered@NLHPC: this research was partially supported by the supercomputing infrastructure of the NLHPC (ECM-02). This research was supported by the high-performance computing system of PIDi-UTEM (SCC-PIDi-UTEM FONDEQUIP-EQM180180). There are no conflicts to declare.Attached Files
Submitted - trapping-an-unusual-pentacoordinate-carbon-atom-in-a-neutral-trialuminum-complex_v2.pdf
Supplemental Material - d1cc04265c1.pdf
Supplemental Material - d1cc04265c2.pdf
Supplemental Material - d1cc04265c3.cif
Files
d1cc04265c2.pdf
Additional details
- Eprint ID
- 109702
- Resolver ID
- CaltechAUTHORS:20210701-165443333
- 1200748
- Fondo Nacional de Desarrollo Científico y Tecnológico (FONDECYT)
- 3210532
- Fondo Nacional de Desarrollo Científico y Tecnológico (FONDECYT)
- 3180073
- Fondo Nacional de Desarrollo Científico y Tecnológico (FONDECYT)
- 1181260
- Fondo Nacional de Desarrollo Científico y Tecnológico (FONDECYT)
- ECM-02
- Laboratorio Nacional de Computación de Alto Rendimiento
- EQM180180
- Comisión Nacional de Investigación Científica y Tecnológica (CONICYT)
- Created
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2021-07-02Created from EPrint's datestamp field
- Updated
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2021-10-07Created from EPrint's last_modified field