Biomass Burning Unlikely to Account for Missing Source of Carbonyl Sulfide

Abstract

Carbonyl sulfide (OCS) provides a proxy for measuring photosynthesis and is the primary background source of stratospheric aerosols. OCS emissions due to biomass burning are a variable and substantial (over 10%) part of the current OCS budget. OCS emission ratios from open burning fires, coupled with 1997–2016 data from the Global Fire Emissions Database (GFED4), yield OCS biomass burning emissions with a global average annual flux of 60 ± 37 Gg(S) year⁻¹. A global box model suggests these emissions are more consistent with observations from global atmospheric composition monitoring networks than fluxes derived from previous synthesis papers. Even after considering the uncertainty in emission factor observations for each category of emissions and the interannual variation in total burned dry matter, the total OCS emissions from open burning are insufficient to account for the large imbalance between current estimates of global OCS sources and sinks.

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