Published August 2019
| public
Conference Paper
Unimolecular chemistry of organic peroxy radicals in the atmosphere
Chicago
Abstract
We review recent exptl. results on the unimol. chem. of org. peroxy radicals. We describe metods for measuring the rate coeffs. and products of this chem. A major focus of this work is to describing the rates and products of H-shift and endocylization reactions in substituted radicals, such as alcs., peroxides derived from alkanes, aldehydes, and biogenically-derived alkenes. We illustrate how the structure of these peroxy radicals, including their stereochem., can inhibit or accelerate the rate of this chem.
Additional Information
© 2019 American Chemical Society.Additional details
- Eprint ID
- 102917
- Resolver ID
- CaltechAUTHORS:20200430-093519375
- Created
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2020-04-30Created from EPrint's datestamp field
- Updated
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2020-04-30Created from EPrint's last_modified field
- Caltech groups
- Division of Geological and Planetary Sciences