Aerosol–photolysis interaction reduces particulate matter during wintertime haze events

Abstract

Aerosol–radiation interaction (ARI) plays a significant role in the accumulation of fine particulate matter (PM_(2.5)) by stabilizing the planetary boundary layer and thus deteriorating air quality during haze events. However, modification of photolysis by aerosol scattering or absorbing solar radiation (aerosol–photolysis interaction or API) alters the atmospheric oxidizing capacity, decreases the rate of secondary aerosol formation, and ultimately alleviates the ARI effect on PM_(2.5) pollution. Therefore, the synergetic effect of both ARI and API can either aggravate or even mitigate PM_(2.5) pollution. To test the effect, a fully coupled Weather Research and Forecasting (WRF)-Chem model has been used to simulate a heavy haze episode in North China Plain. Our results show that ARI contributes to a 7.8% increase in near-surface PM_(2.5). However, API suppresses secondary aerosol formation, and the combination of ARI and API results in only 4.8% net increase of PM_(2.5). Additionally, API increases the solar radiation reaching the surface and perturbs aerosol nucleation and activation to form cloud condensation nuclei, influencing aerosol–cloud interaction. The results suggest that API reduces PM_(2.5) pollution during haze events, but adds uncertainties in climate prediction.

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