Published March 2020
| public
Conference Paper
Electronic structures and redox properties of boronated cyanometalates
- Creators
- Gray, Harry B.
- McNicholas, Brendon James
Abstract
We have synthesized and structurally characterized homoleptic and heteroleptic tris(pentafluorophenyl)borane adducts of iron, ruthenium, and osmium cyanides. The III/II formal potentials are more than 2.0 V higher in the boronated octahedral complexes; and, in the boronated heteroleptic complexes, the MLCT excited triplets are relatively long-lived (he MLCT absorptions are dramatically blue-shifted).The boronated homoleptic complexes, which are electrochem. reversible, exhibit energy efficiencies of 80% in nonaq. redox flow batteries; and the boronated heteroleptic complexes exhibit cell potentials over 3.0 V in sym-rf batteries.
Additional Information
© 2020 American Chemical Society.Additional details
- Eprint ID
- 101354
- Resolver ID
- CaltechAUTHORS:20200219-075302879
- Created
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2020-02-19Created from EPrint's datestamp field
- Updated
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2020-03-09Created from EPrint's last_modified field