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Published March 10, 2020 | public
Journal Article

Teaching Thermodynamics with the Quantum Volume

Yu, Ted H. ORCID icon

Abstract

The author introduces the concept of the quantum volume into thermodynamics teaching. A new derivation of the basic part of the Sackur–Tetrode equation uses the microcanonical ensemble instead of the math-heavy canonical ensemble. Entropy diagrams, based on the binomial distribution, visualize the ratio between the quantum volume and system volume.

Additional Information

© 2020 American Chemical Society and Division of Chemical Education, Inc. Received: August 8, 2019; Revised: November 19, 2019; Published: January 27, 2020. The author would like to thank Brent Fultz for useful discussions. The author declares no competing financial interest.

Additional details

Created:
August 19, 2023
Modified:
October 19, 2023