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Published March 1, 2020 | Supplemental Material
Journal Article Open

The spatial footprint of hydrothermal scavenging on ²³⁰Th_(XS)-derived mass accumulation rates

Abstract

Mid-ocean ridges are valuable archives of sedimentary flux records used to investigate atmospheric, oceanographic, and solid Earth responses to climate variability. Constant flux proxies, such as extraterrestrial helium-3 (³He_(ET)) and excess thorium-230 (²³⁰Th_(XS)), constrain vertical mass accumulation rates independent of the biases associated with lateral sediment transport and age model resolution. However, thorium scavenging by hydrothermal particles can perturb local ²³⁰Th_(XS) deposition and complicate its application as a constant flux proxy in near-ridge environments. We characterize the footprint of hydrothermal scavenging on sedimentary ²³⁰Th_(XS) using coupled ³He_(ET)-²³⁰Th_(XS) analyses in cores from the Mid-Atlantic Ridge and the Juan de Fuca Ridge. Samples deposited >10 km from the Juan de Fuca Ridge indicate reliable off-axis behavior of both constant flux proxies. In contrast, samples deposited <10 km from the Juan de Fuca Ridge axis and within the axial valley of the Mid-Atlantic ridge suggest 50-80% deficits in sedimentary ²³⁰Th_(XS) relative to its production rate. These deficits contrast with sedimentary ²³⁰Th_(XS) surpluses recently observed on the East Pacific Rise. The spatial footprint of hydrothermal scavenging varies globally and temporally, likely as a function of the intensity of local hydrothermal activity. The combined ridge data suggest that near-vent sediments (within ∼5 km, but variable by ridge) receive relatively high ²³⁰Th_(XS) deposition rates as a direct result of hydrothermal particle scavenging, while more distal sediments receive relatively low ²³⁰Th_(XS) deposition rates due to diffusive loss of overlying seawater ²³⁰Th_(XS) towards the vent. Aside from the East Pacific Rise, far-field sediments are likely to exhibit typical ²³⁰Th_(XS) deposition rates at distances greater than ∼10 km of the ridge axis. However, ²³⁰Th_(XS) systematics within the axial valleys of slow-spreading ridges may be complicated by other factors. Combined ³HeET-²³⁰Th_(XS) studies at multiple ridges are needed to further characterize the nature of hydrothermal scavenging and to evaluate the potential of sedimentary ²³⁰Th_(XS) anomalies to record large-scale variability in past hydrothermal activity.

Additional Information

© 2020 Elsevier Ltd. Received 15 October 2019, Accepted 7 January 2020, Available online 16 January 2020. All the data in this paper are available in the references and supplementary tables. We thank F. Apen and Z. Chen for technical assistance with helium isotope and ICP-MS analyses and S. Jones and B. Boulahanis for valuable discussion. We additionally thank D. Lund and D. McGee for their valuable and thoughtful reviews. We acknowledge financial support from the National Science Foundation grant AGS-1338832. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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Supplemental Material - 1-s2.0-S0016703720300193-mmc1.pdf

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Created:
August 19, 2023
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October 18, 2023