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Published May 4, 2019 | Supplemental Material
Journal Article Open

A general strategy for visible-light decaging based on the quinone cis-alkenyl lock

Abstract

Combining the fast thermal cyclization of o-coumaric acid derivatives with the intramolecular photoreduction of quinones gives new visible-light photoremovable protecting groups absorbing well above 450 nm.

Additional Information

© 2019 The Royal Society of Chemistry. The article was received on 05 Feb 2019, accepted on 28 Mar 2019 and first published on 05 Apr 2019. We thank Scott Virgil of the Caltech Center for Catalysis and Chemical Synthesis in the Beckman Institute at Caltech for technical assistance. This work was supported by the W. M. Keck Foundation. This work is dedicated to Ron Raines on the occasion of his 60th birthday. There are no conflicts to declare.

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