Published April 2019
| public
Conference Paper
Electronic structures and electrochemistry of boronated cyanometalates
Abstract
We have synthesized and structurally characterized a series of organoboron-modified cyanometalates. The redn. potentials of these modified metal complexes span an exceptionally wide range, owing to variations in the electronic properties of the appended organoboron derivs. Selected highly sol. redox pairs exhibit electrochem. reversibility over a 2.1 V range in non-aq. solvents, making them excellent candidates for non-aq. redox flow batteries. Our model flow battery systems exhibit near unity Coulombic efficiencies and high energy efficiencies.
Additional Information
© 2019 American Chemical Society.Additional details
- Eprint ID
- 94108
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- CaltechAUTHORS:20190325-095401293
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2019-03-25Created from EPrint's datestamp field
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2019-11-22Created from EPrint's last_modified field