Published March 20, 2002
| Supplemental Material
Journal Article
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Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy: Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex
Abstract
Methine (CH) transfer to an open coordination site was achieved in one pot by titanium(III) abstraction of Cl from 7-chloronorbornadiene, radical capture by Mo, and benzene extrusion. This efficient Mo methylidyne synthesis permitted elaboration to an anionic phosphaisocyanide derivative upon deprotonation, functionalization with dichlorophenylphosphine, and ultimate reduction.
Additional Information
© 2002 American Chemical Society. Received October 10, 2001. For support of this work, the authors are grateful to the National Science Foundation (CHE-9988806), the Packard Foundation (Fellowship to C.C.C., 1995-2000), and the National Science Board (Alan T. Waterman award to C.C.C., 1998). T.A. thanks MIT's UROP (Undergraduate Research Opportunities Program) for funding. The authors thank a referee for drawing attention to ref 12.Attached Files
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Additional details
- Eprint ID
- 90662
- DOI
- 10.1021/ja017278r
- Resolver ID
- CaltechAUTHORS:20181106-085445876
- CHE-9988806
- NSF
- David and Lucile Packard Foundation
- Massachusetts Institute of Technology (MIT)
- Created
-
2018-11-06Created from EPrint's datestamp field
- Updated
-
2021-11-16Created from EPrint's last_modified field