Published January 17, 1986
| public
Journal Article
Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy
Chicago
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Abstract
The electronic states of the unsaturated organometallic carbene CrCH_2^+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, ^6B_1, and ^6A_1 at 0.78 and 0.82 eV respectively, above the ^4B_1 ground state of CrCH_2^+.
Additional Information
© 1986 Published by Elsevier B.V. Received 4 November 1985. Arthur Amos Noyes Laboratory of Chemical Physics Contribution No. 7320. This work was supported by the National Science Foundation under Grants No. CHE-8318041 (WAG), CHE-8020464 (MTB) and CHE-8407857 (JLB). Support from the Shell Development Company (WAG) and the Atlantic Richfield Foundation (MAH graduate fellowship) is gratefully acknowledged. EAC acknowledges a National Science Foundation predoctoral fellowship (1982-1985).Additional details
- Eprint ID
- 88410
- DOI
- 10.1016/0009-2614(86)80064-1
- Resolver ID
- CaltechAUTHORS:20180731-152042927
- NSF
- CHE-8318041
- NSF
- CHE-8020464
- NSF
- CHE-8407857
- Shell Development Company
- Atlantic Richfield Foundation
- NSF Predoctoral Fellowship
- Created
-
2018-07-31Created from EPrint's datestamp field
- Updated
-
2021-11-16Created from EPrint's last_modified field
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7320