Published June 13, 1955
| public
Journal Article
An Electron Diffraction Investigation of Dimethyl Selenide
Chicago
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Abstract
The results of an electron diffraction investigation of (CH_3)_2Se arc C-H/Se-C, 1.09/1.97 ( assumed); Se-C, 1.977 ± 0.012 Å.; Se•••H, 2.571 ± 0.034 Å.; C•••C, 2.98 ± 0.23 Å.; ∠C-Se-C, 98 ± 10°; and ∠Se-C-H, 110.5 ± 3.5°. The selenium-carbon distance of 1.98 Å. leads to a single-bond radius for selenium of 1.22 Å., which is considerably larger than the value 1.17 A. chosen by Pauling.
Additional Information
© 1955 American Chemical Society. Received January 17, 1955. The support of this work by the Office of Naval Research under Contract N6 onr 24423 is gratefully acknowledged.Additional details
- Eprint ID
- 88269
- DOI
- 10.1021/ja01616a005
- Resolver ID
- CaltechAUTHORS:20180725-111211759
- Office of Naval Research (ONR)
- N6 onr 24423
- Created
-
2018-07-25Created from EPrint's datestamp field
- Updated
-
2021-11-16Created from EPrint's last_modified field
- Other Numbering System Name
- Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 1967