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Published December 1, 2011 | Accepted Version
Journal Article Open

Cu-ZSM-5: A biomimetic inorganic model for methane oxidation

Abstract

The present work highlights recent advances in elucidating the methane oxidation mechanism of inorganic Cu-ZSM-5 biomimic and in identifying the reactive intermediates that are involved. Such molecular understanding is important in view of upgrading abundantly available methane, but also to comprehend the working mechanism of genuine Cu-containing oxidation enzymes.

Additional Information

© 2011 Elsevier. Available online 14 November 2011. This work was performed within the framework of FWO (G.0596.11), IAP (Belspo), ERIC and Methusalem (long-term structural funding by the Flemish Government) projects. E.I.S. acknowledges the NIH (Grant DK-31450), and R.G.H. acknowledges a Gerhard Casper Stanford Graduate Fellowship.

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