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Published August 13, 2014 | Supplemental Material
Journal Article Open

A Stable Polyaniline-Benzoquinone-Hydroquinone Supercapacitor

Abstract

A Polyaniline‐Supercapacitor with quinone electrolytes remains stable over 50 000 galvanostatic charge‐discharge cycles. The quinones provide superior stability by preventing the conversion of porous polyaniline to a highly reactive state. Our work shows that highly stable polymer‐supercapacitors can be engineered by combining electrochemically active polymers and redox‐active electrolytes with concerted electrochemical properties.

Additional Information

© 2014 WILEY‐VCH. Received: March 1, 2014. Revised: May 9, 2014. Published online: June 13, 2014. This work was supported by the Department of Energy Office of Basic Energy Sciences (DE‐FG02–08ER46535) and by the Swiss National Science Foundation (SNF‐PBBSP2–144291) and the battery fabrication and testing lab, part of the MRL Shared Experimental Facilities, supported by the MRSEC Program of the NSF under Award No. DMR 1121053; a member of the NSF‐funded Materials Research Facilities Network. Fellowship support to KAS from the ConvEne IGERT Program of the National Science Foundation (DGE 0801627), and support from the Fred and Linda R. Wudl Chair is gratefully acknowledged.

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