Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes

Creators: Chang, Christopher J.; Low, Donald W.; Gray, Harry B.

Abstract

Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear μ-nitrido-activated complex accounts satisfactorily for the observed kinetics data.

Additional Information

© 1997 American Chemical Society. Received August 22, 1996. We thank John Bercaw, Justin DuBois, and Jay Winkler for helpful discussions and Fred Anson for the loan of a thermostatable cell holder. C.J.C. participated in the Summer Undergraduate Research Fellowship (SURF) program at Caltech during 1995 and 1996. D.W.L. acknowledges a fellowship from the Parsons Foundation. This work was supported by the NSF.

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Resource type: Journal Article
Publisher: American Chemical Society
Published in: Inorganic Chemistry, 36(3), 270-271, ISSN: 0020-1669.

Created:: August 19, 2023
Modified:: October 18, 2023