Published September 24, 1997
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Journal Article
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Electroreduction of O_2 to H_2O at Unusually Positive Potentials Catalyzed by the Simplest of the Cobalt Porphyrins
Chicago
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Abstract
Simple cobalt porphine, adsorbed on graphite electrodes, catalyzes the direct reduction of O_2 to H_2O, while most other monomeric cobalt porphyrins do not. The surprising behavior of cobalt porphine suggests possible new strategies for the design of electrocatalysts for the reduction of O_2 to H_2O using structurally similar but more oxidation-resistant analogs.
Additional Information
© 1997 American Chemical Society. Received May 1, 1997. Publication Date (Web): September 24, 1997. This work was supported by the National Science Foundation.Attached Files
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- Alternative title
- Electroreduction of O2 to H2O at Unusually Positive Potentials Catalyzed by the Simplest of the Cobalt Porphyrins
- Eprint ID
- 86565
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- CaltechAUTHORS:20180523-110226758
- NSF
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