Published August 3, 1998
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Journal Article
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Synthesis and Characterization of New Ruthenium-Based Olefin Metathesis Catalysts Coordinated with Bidentate Schiff-Base Ligands
Chicago
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Abstract
A novel series of Schiff-base-substituted ruthenium carbene complexes have been prepared by the treatment of RuCl_2(=CHPh)(PCy_3)_2 with a variety of Schiff-base ligands as the thallium salts. Modification of the Schiff-base electronic and/or structural substituents allowed for the tuning of the complexes activities in olefin metathesis reactions. The structures of the complexes were unambiguously characterized by NMR studies and X-ray analysis. These newly prepared complexes are highly stable to air, moisture, and temperature and even exhibit catalytic activity in polar protic solvents.
Additional Information
© 1998 American Chemical Society. Received October 17, 1997. Support has been provided by the National Institute of Health. L.J.II is grateful to the NIH for a Postdoctoral Fellowship.Attached Files
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Additional details
- Eprint ID
- 86477
- DOI
- 10.1021/om970910y
- Resolver ID
- CaltechAUTHORS:20180518-160600771
- NIH Postdoctoral Fellowship
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2018-05-21Created from EPrint's datestamp field
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2021-11-15Created from EPrint's last_modified field