Published March 29, 1999
| Supplemental Material
Journal Article
Open
Catalytic Dehalogenation of Aryl Chlorides Mediated by Ruthenium(II) Phosphine Complexes
Chicago
An error occurred while generating the citation.
Abstract
The catalytic dechlorination of aryl chlorides performed by RuHCl(H_2)_2(PCy_3)_2 and RuH_2(H_2)_2(PCy_3)_2 in alcohols is rapid and complete within 1 h. The mechanism involves a transfer hydrogenation step with participation of the alcohol. The system exhibits significant functional group tolerance. The catalyst can be generated in situ from [RuCl_2(COD)]_x (COD = cyclooctadiene) and 2 equiv of phosphine (PCy_3 or P^iPr_3). Catalytic conversions are similar to those observed when an isolated precatalyst is used. Mechanistic considerations and the scope of the process are discussed.
Additional Information
© 1999 American Chemical Society. Received August 11, 1998. The National Science Foundation is gratefully acknowledged for support of this work.Attached Files
Supplemental Material - om980682n_s.pdf
Files
om980682n_s.pdf
Files
(22.9 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:f92c5cf9af17fc6c60e3e8bd551a4c5b
|
22.9 kB | Preview Download |
Additional details
- Eprint ID
- 86471
- Resolver ID
- CaltechAUTHORS:20180518-152454626
- NSF
- Created
-
2018-05-21Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field