Published November 1, 1994
| public
Journal Article
Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene
- Creators
- Wu, Zhe
-
Grubbs, Robert H.
Chicago
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Abstract
Near monodispersed linear polyethylene can be synthesized y hydrogenation of polybutadiene prepared by the living ring-opening metathesis polymerization (ROMP) of cyclobutene. The polyethylene is highly crystalline, as determined by powder X-ray diffraction, and defect free, as shown by spectroscopic data. Living polycyclobutene can also react with anthracene dialdehyde to give a labeled polymer and with norbornene to produce a block copolymer.
Additional Information
© 1994 American Chemical Society. Received June 1, 1994; Revised Manuscript Received August 8, 1994. We gratefully acknowledge the financial support from the National Science Foundation.Additional details
- Eprint ID
- 85285
- Resolver ID
- CaltechAUTHORS:20180313-143927774
- NSF
- Created
-
2018-03-13Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arnold and Mabel Laboratories of Chemical Synthesis
- Other Numbering System Identifier
- 8953