Catalytic Iridium-Based Janus Micromotors Powered by Ultralow Levels of Chemical Fuels
- Creators
-
Gao, Wei
- Pei, Allen
-
Dong, Renfeng
- Wang, Joseph
Abstract
We describe catalytic micromotors powered by remarkably low concentrations of chemical fuel, down to the 0.0000001% level. These Janus micromotors rely on an iridium hemispheric layer for the catalytic decomposition of hydrazine in connection to SiO_2 spherical particles. The micromotors are self-propelled at a very high speed (of ∼20 body lengths s^(–1)) in a 0.001% hydrazine solution due to osmotic effects. Such a low fuel concentration represents a 10 000-fold decrease in the level required for common catalytic nanomotors. The attractive propulsion performance, efficient catalytic energy-harvesting, environmentally triggered swarming behavior, and magnetic control of the new Janus micromotors hold considerable promise for diverse practical applications.
Additional Information
© 2014 American Chemical Society. Received 20 December 2013. Published online 29 January 2014. Published in print 12 February 2014. This project received support from the Defense Threat Reduction Agency-Joint Science and Technology Office for Chemical and Biological Defense (Grant No. HDTRA1-13-1-0002). W.G. is a HHMI International Student Research fellow. The authors also thank R. Tam and I. Rozen for their help. The authors declare no competing financial interest.Attached Files
Supplemental Material - ja413002e_si_001.pdf
Supplemental Material - ja413002e_si_002.mpg
Supplemental Material - ja413002e_si_003.mpg
Supplemental Material - ja413002e_si_004.mpg
Supplemental Material - ja413002e_si_005.mpg
Supplemental Material - ja413002e_si_006.mpg
Supplemental Material - ja413002e_si_007.mpg
Supplemental Material - ja413002e_si_008.mpg
Files
Name | Size | Download all |
---|---|---|
md5:b5ee34e654b7b6290d48ec37afd5034a
|
12.0 MB | Download |
md5:2c754c5334c667d673615e7cf53fe2f6
|
7.3 MB | Download |
md5:8b504aad4597e54888f0dad48e515d42
|
48.3 kB | Preview Download |
md5:42841a8a5c0639969f91f80f76302e32
|
452.6 kB | Download |
md5:8e29c294a4806025b4772b9ea17d7392
|
636.9 kB | Download |
md5:af220d8c0e115efd80086b6671f5225d
|
1.6 MB | Download |
md5:8b8854cb7c59ecd1c0ac249390886d7b
|
968.7 kB | Download |
md5:39f0a2bb089e4d55d315a91230eadcb2
|
1.2 MB | Download |
Additional details
- Eprint ID
- 84471
- DOI
- 10.1021/ja413002e
- Resolver ID
- CaltechAUTHORS:20180123-095921744
- Defense Threat Reduction Agency (DTRA)
- HDTRA1-13-1-0002
- Howard Hughes Medical Institute (HHMI)
- Created
-
2018-02-01Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field