Published January 21, 2018
| Supplemental Material
Journal Article
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Mild electrochemical synthesis of metal phosphides with dibenzo-7-phosphanorbornadiene derivatives: mechanistic insights and application to proton reduction in water
- Creators
- Shida, Naoki
-
Buss, Joshua A.
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Agapie, Theodor
Chicago
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Abstract
Transition metal phosphide films were synthesized using a mild electrochemical method. Dibenzo-7-phosphanorbornadiene derivatives (XPA) are introduced as versatile precursors to amorphous metal phosphide electrocatalysts for proton reduction in acidic water. Homogeneous model reactions reveal distinct reactivity between XPA and nickel in different oxidation states, with Ni(0) resulting in Ni_xP_y formation.
Additional Information
© 2018 The Royal Society of Chemistry. Received 23rd November 2017, Accepted 19th December 2017, First published on 20th December 2017. We thank Lawrence M. Henling and Dr Mike Takase for crystallographic assistance, Dr David Vandervelde for help with NMR experiments. T. A. thanks Caltech and the Dreyfus Foundation for funding. Parts of these studies were funded by NSF CHE-1151918 and King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia, offered under the KFUPM-Caltech Research Collaboration. N. S. is grateful for a Grant-in-Aid for JSPS Research Fellow (No. 16J07350) and J. A. B. for an NSF graduate research fellowship. There are no conflicts to declare.Attached Files
Supplemental Material - c7cc09003j1_si.pdf
Supplemental Material - c7cc09003j2.cif
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Additional details
- Eprint ID
- 84172
- Resolver ID
- CaltechAUTHORS:20180108-142905197
- Caltech
- Camille and Henry Dreyfus Foundation
- NSF
- CHE-1151918
- King Fahd University of Petroleum and Minerals (KFUPM)
- Japan Society for the Promotion of Science (JSPS)
- 16J07350
- NSF Graduate Research Fellowship
- Created
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2018-01-08Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field