Published October 12, 2017
| public
Journal Article
Driving Force Dependence of Electron Transfer from Electronically Excited [Ir(COD)(μ-Me_2pz)]_2 to Photo-Acid Generators
Chicago
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Abstract
We report the rates of electron transfer (ET) reactions of electronically excited [Ir(COD)(μ-Me_2pz)]_2 with onium salt photoacid generators (PAGs). The reduction potentials of the PAGs span a large electrochemical window that allows determination of the driving force dependence of the ET reactions. Rate constants of ET from electronically excited [Ir(COD)(μ-Me_2pz)]_2 to onium PAGs are determined by the reaction driving force until the diffusion limit in acetonitrile is reached.
Additional Information
© 2017 American Chemical Society. Received: August 4, 2017; Revised: September 10, 2017; Published: September 28, 2017. This work was supported in part by the National Science Foundation Center for Chemical Innovation in Solar Fuels (Grant CHE-1305124), Center for Chemical Innovation postdoctoral fellowship to W.S. This work was also funded in part by The Dow Chemical Company through a university partnership program (Agreement 227027AH). The authors declare no competing financial interest.Additional details
- Eprint ID
- 81922
- DOI
- 10.1021/acs.jpca.7b07777
- Resolver ID
- CaltechAUTHORS:20170929-115128097
- NSF
- CHE-1305124
- Dow Chemical Company
- 227027AH
- Created
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2017-09-29Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field