Published October 21, 2017
| Supplemental Material
Journal Article
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Two-photon spectroscopy of tungsten(0) arylisocyanides using nanosecond-pulsed excitation
Chicago
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Abstract
The two-photon absorption (TPA) cross sections (δ) for tungsten(0) arylisocyanides (W(CNAr)6) were determined in the 800–1000 nm region using two-photon luminescence (TPL) spectroscopy. The complexes have high TPA cross sections, in the range 1000–2000 GM at 811.8 nm. In comparison, the cross section at 811.8 nm for tris-(2,2′-bipyridine)ruthenium(II), [Ru(bpy)_3]^(2+), is 7 GM. All measurements were performed using a nanosecond-pulsed laser system.
Additional Information
© 2017 The Royal Society of Chemistry. The article was received on 19 Jul 2017, accepted on 11 Sep 2017 and first published on 21 Sep 2017. Research was supported by CCI Solar Fuels (NSF CHE-1305124) and the Arnold and Mabel Beckman Foundation. There are no conflicts to declare.Attached Files
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Additional details
- Eprint ID
- 81675
- Resolver ID
- CaltechAUTHORS:20170921-104309376
- NSF
- CHE-1305124
- Arnold and Mabel Beckman Foundation
- Created
-
2017-09-21Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field
- Caltech groups
- CCI Solar Fuels