Published October 14, 2005
| Accepted Version + Supplemental Material
Journal Article
Open
Palladium-Catalyzed Synthesis of N-Vinyl Pyrroles and Indoles
- Creators
- Movassaghi, Mohammad
- Ondrus, Alison E.
Chicago
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Abstract
A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is described. Cyclic and acyclic vinyl triflates along with nonnucleophilic azaheterocycles were found to be substrates for this palladium-catalyzed synthesis of N-vinyl pyrrole and indole derivatives.
Additional Information
© 2005 American Chemical Society. Received July 13, 2005. M.M. is a Dale F. and Betty Ann Frey Damon Runyon Scholar supported by the Damon Runyon Cancer Research Foundation (DRS-39-04). M.M. is a Firmenich Assistant Professor of Chemistry. A.E.O. acknowledges a Robert T. Haslam Presidential Graduate Fellowship. We thank Mr. Matthew P. Rainka and Professor Stephen L. Buchwald for helpful discussions. We thank Mr. Robert W. Sindelar for early contributions to this study. We acknowledge generous financial support by the donors of the American Chemical Society Petroleum Research Fund (40631G1), MIT, Amgen Inc., and NIH-NIGMS (GM074825).Attached Files
Accepted Version - nihms881227.pdf
Supplemental Material - jo051450isi20050810_022543.pdf
Files
nihms881227.pdf
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Additional details
- PMCID
- PMC5548004
- Eprint ID
- 81057
- DOI
- 10.1021/jo051450i
- Resolver ID
- CaltechAUTHORS:20170901-082320777
- Damon Runyon Cancer Research Foundation
- DRS-39-04
- Robert T. Haslam Presidential Graduate Fellowship
- American Chemical Society Petroleum Research Fund
- 40631G1
- Massachusetts Institute of Technology (MIT)
- Amgen
- NIH
- GM074825
- Created
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2017-09-01Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field