Published January 31, 2005
| Supplemental Material
Journal Article
Open
A Ruthenium Olefin Metathesis Catalyst with a Four-Membered N-Heterocyclic Carbene Ligand
Abstract
The first ruthenium olefin metathesis catalyst bearing a four-membered N-heterocyclic carbene (5) was synthesized and characterized by NMR spectroscopy and X-ray crystallography. The synthesis of a (carbene)carbonylrhodium complex (6) was also reported, allowing the study of the electronic properties of this new carbene ligand. The complex 5 was screened toward different olefin metathesis reactions, and it showed a slow reactivity.
Additional Information
© 2005 American Chemical Society. Received 22 November 2004. Published online 31 December 2004. Published in print 1 January 2005. We thank Lawrence M. Henling, Michael W. Day, and the ACS PRF summer class for X-ray crystallography studies. We acknowledge also Materia for providing chemicals and Dr. Christiane Meyer-Marti for the GC conditions on the CM reaction. E.D.-A. is grateful to the Ministère des Affaires Etrangères of France for a Lavoisier postdoctoral fellowship. This work was also supported by the National Science Foundation.Attached Files
Supplemental Material - om049092hsi20041219_022303.pdf
Files
om049092hsi20041219_022303.pdf
Files
(112.0 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:95df984896633a2e360985103e73a5e6
|
112.0 kB | Preview Download |
Additional details
- Eprint ID
- 79400
- DOI
- 10.1021/om049092h
- Resolver ID
- CaltechAUTHORS:20170726-092036399
- Ministère des Affaires Etrangères
- NSF
- Created
-
2017-07-26Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field