Published February 13, 2006
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Journal Article
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Improved One-Pot Synthesis of Mixed Methyl−Aryl Platinum(II) Diimine Complexes
Chicago
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Abstract
A general one-pot synthetic route for mixed methyl−aryl Pt(II) diimine complexes is described. Performing the alkylation in neat Me_2S instead of ether or THF greatly reduces the amount of comproportionation products otherwise formed, diminishes separation problems, and improves yields. Treatment of the intermediate methyl−aryl complexes (Me_2S)_2Pt(Me)(Ar) with diimines (N−N) furnishes the methyl−aryl Pt(II) diimine complexes (N−N)Pt(Me)(Ar) in 76−84% yields. The Pt methyl−phenyl complex [p-Tol-N ═ VC(Me)C(Me) ═ N-p-Tol]Pt(Me)(Ph) has been characterized by X-ray diffraction.
Additional Information
© 2006 American Chemical Society. Received 18 October 2005. Published online 17 January 2006. Published in print 1 February 2006. M.L. thanks the Norwegian Research Council (NFR) for generous funding and the U.S.-Norway Fulbright Foundation for a grant allowing him to spend 7 months at the California Institute of Technology.Attached Files
Supplemental Material - om050899zsi20051018_100519.cif
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Additional details
- Eprint ID
- 79345
- DOI
- 10.1021/om050899z
- Resolver ID
- CaltechAUTHORS:20170725-135756147
- Norwegian Research Council
- Fulbright Foundation
- Created
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2017-07-25Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field