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Published November 13, 2001 | Supplemental Material
Journal Article Open

Poly(aniline boronic acid): A New Precursor to Substituted Poly(aniline)s

Abstract

A novel strategy for preparing a wide range of substituted poly(aniline)s from a single precursor is described. This approach relies on a boron activation/electrophilic displacement reaction resulting in ipso-substitution. Specifically, we demonstrate this strategy to prepare a few of the many possible structures that can be generated from poly(aniline boronic acid), including poly(hydroxyaniline) and halogenated poly(aniline)s. The ability to tune the properties of poly(aniline) through the generation of these new structures will be useful in diverse fields where poly(aniline) is used ranging from polymer-based electronics to sensors.

Additional Information

© 2001 American Chemical Society. Received 11 September 2001. Published online 10 October 2001. Published in print 1 November 2001. This work was supported by the Arnold and Mabel Beckman Foundation.

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