Published June 25, 2008
| Supplemental Material
Journal Article
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Iridium Corroles
Chicago
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Abstract
This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 Å for 1 and 0.0325 Å for 2), the UV−vis spectra display a split Soret band with a shoulder attributable to an MLCT transition, and cyclic voltammetry reveals that the iridium(II) oxidation state cannot be accessed, while the oxidation to formal iridium(IV) complexes is achieved at much lower potentials than in other coordination environments.
Additional Information
© 2008 American Chemical Society. Received February 11, 2008. Publication Date (Web): May 31, 2008. This work was supported by the US-Israel BSF (Z.G. and H.B.G.), BP, NSF, CCSER (Gordon and Betty Moore Foundation), and the Arnold and Mabel Beckman Foundation (H.B.G.).Attached Files
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Supplemental Material - ja801049t-file004.pdf
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Additional details
- Eprint ID
- 77417
- DOI
- 10.1021/ja801049t
- Resolver ID
- CaltechAUTHORS:20170512-130427477
- Binational Science Foundation (USA-Israel)
- BP
- NSF
- Caltech Center for Sustainable Energy Research
- Gordon and Betty Moore Foundation
- Arnold and Mabel Beckman Foundation
- Created
-
2017-05-12Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field