Published September 13, 2006
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Journal Article
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Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium Interaction
Abstract
The synthesis, structure, and performance of new ruthenium-based olefin metathesis catalysts, featuring fluorinated NHC ligands are presented. The introduction of halogen atoms into the N-heterocyclic carbene ligand profoundly alters the catalytic activity and can afford a more efficient catalyst. Structural investigations suggest that a fluorine−ruthenium interaction is responsible for this increased activity.
Additional Information
© 2006 American Chemical Society. Received June 21, 2006. Publication Date (Web): August 22, 2006. Larry M. Henling is acknowledged for X-ray crystallographic analysis. We thank Donde Anderson and Prof. Daniel J. O'Leary for helpful discussions and NMR studies. T.R. thanks the German Academic Exchange Service (DAAD) for a postdoctoral fellowship.Attached Files
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Additional details
- Eprint ID
- 77317
- Resolver ID
- CaltechAUTHORS:20170509-160741000
- Deutscher Akademischer Austauschdienst (DAAD)
- Created
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2017-05-16Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field