Published June 28, 2017
| Supplemental Material + Accepted Version
Journal Article
Open
A CaMn₄O₂ model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand
- Creators
-
Lee, Heui Beom
-
Tsui, Emily Y.
-
Agapie, Theodor
Abstract
Using a new multinucleating ligand featuring two dipyridyl alkoxide moieties and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as a precursor for the synthesis of a pentanuclear CaMn₄O₂ cluster (3) with the same metal stoichiometry as the biological OEC.
Additional Information
© 2017 The Royal Society of Chemistry. The article was received on 27 Mar 2017, accepted on 25 Apr 2017 and first published on 25 Apr 2017. This work was supported by the NIH (R01-GM102687B), Caltech, a Sandia Campus Executive Fellowship (E. Y. T.) and a Dreyfus fellowship (T. A.).Attached Files
Accepted Version - nihms875402.pdf
Supplemental Material - c7cc02313h1_si.pdf
Supplemental Material - c7cc02313h2.cif
Files
nihms875402.pdf
Additional details
- PMCID
- PMC5508601
- Eprint ID
- 77290
- Resolver ID
- CaltechAUTHORS:20170509-083819492
- R01-GM102687B
- NIH
- Caltech
- Sandia National Laboratories
- Camille and Henry Dreyfus Foundation
- Created
-
2017-05-12Created from EPrint's datestamp field
- Updated
-
2022-03-25Created from EPrint's last_modified field