Published July 3, 2008
| Supplemental Material
Journal Article
Open
Olefin Metathesis Catalyst: Stabilization Effect of Backbone Substitutions of N-Heterocyclic Carbene
- Creators
- Chung, Cheol K.
-
Grubbs, Robert H.
Chicago
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Abstract
Ruthenium olefin metathesis catalysts bearing an N-phenyl-substituted N-heterocyclic carbene (NHC) ligand that are resistant to decomposition through C−H activation have been prepared and tested in ring closing metathesis (RCM), cross metathesis (CM), and ROMP reactions. The N,N′-diphenyl-substituted NHC complex proved to be one of the most efficient catalysts in RCM to form tetrasubstituted olefins.
Additional Information
© 2008 American Chemical Society. Received 10 April 2008. Published online 30 May 2008. Published in print 3 July 2008. This research was supported by the National Institutes of Health. The authors thank Larry M. Henling and Dr. Michael W. Day, Beckman Institute for X-ray crystallographic analysis. Dr. Jean-Baptiste Bourg and Dr. Ian C. Stewart, California Institute of Technology, are greatly acknowledged for helpful discussion.Attached Files
Supplemental Material - ol800824h-file002.pdf
Supplemental Material - ol800824h-file003.cif
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Additional details
- Eprint ID
- 76948
- Resolver ID
- CaltechAUTHORS:20170426-110234910
- Created
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2017-04-26Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field