Published July 25, 2007
| Supplemental Material
Journal Article
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Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers
Abstract
A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.
Additional Information
© 2007 American Chemical Society. Received April 10, 2007. Publication Date (Web): June 27, 2007. We would like to thank Drs. Stuart Cantrill, Al Nelson, and Anna Sanchez for useful discussions. The ruthenium metathesis catalyst was received as a generous gift from Materia. We thank Lawrence M. Henling and Dr. Michael W. Day for the X-ray crystallographic data. The work was supported by the Office of Naval Research through its MURI Program.Attached Files
Supplemental Material - ja0725100si20070410_112753.cif
Supplemental Material - ja0725100si20070523_044613.pdf
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Additional details
- Eprint ID
- 76807
- Resolver ID
- CaltechAUTHORS:20170421-090622527
- Office of Naval Research (ONR)
- Created
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2017-04-21Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field