Published May 21, 2003
| Supplemental Material
Journal Article
Open
The First Suzuki Cross-Couplings of Aryltrimethylammonium Salts
- Creators
- Blakey, Simon B.
- MacMillan, David W. C.
Abstract
The first Suzuki cross-coupling reaction of aryltrimethylammonium triflates based on the use of an IMes·Ni(0) catalyst system is described. A wide range of electron-withdrawing and electron-donating substituents are tolerated on both the aryltrimethylammonium triflate and the boronic acid components of this reaction. In addition to arylboronic acids, the scope of the reaction is extended to encompass both boronate esters and alkenylboranes. This methodology constitutes a novel, mild method to activate anilines for metal-catalyzed cross-coupling reactions.
Additional Information
© 2003 American Chemical Society. Received 27 February 2003. Published online 29 April 2003. Published in print 1 May 2003. Support was provided by a research foundation grant from Bristol-Myers Squibb.Attached Files
Supplemental Material - ja034908bsi20030402_044412.pdf
Files
ja034908bsi20030402_044412.pdf
Files
(48.5 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:50d0dd96b1dc9fc2f1dfd08b15d73449
|
48.5 kB | Preview Download |
Additional details
- Eprint ID
- 76684
- DOI
- 10.1021/ja034908b
- Resolver ID
- CaltechAUTHORS:20170419-111658044
- Bristol-Myers Squibb
- Created
-
2017-04-19Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field