Published February 5, 2003
| public
Journal Article
Aerobic Oxidations Catalyzed by Chromium Corroles
Chicago
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Abstract
Oxochromium(V) complexes of 5,10,15-tris(pentafluorophenyl)corrole and brominated derivatives oxygenate substrates (triphenylphosphine and norbornene) with concomitant production of chromium(III). Regeneration of Cr^VO by reaction of dioxygen with Cr^(III) completes an aerobic catalytic cycle, with very large solvent effects; in acetonitrile, rapid initial turnovers observed initially are shut down by formation of Cr^(IV)O, while in toluene, THF, and methanol, relatively slow reactions are further inhibited by product formation.
Additional Information
© 2003 American Chemical Society. Received 20 August 2002. Published online 14 January 2003. Published in print 1 February 2003. This research was supported by the Israel Science Foundation under Grant 368/00 (Z.G.), the ACS Petroleum Research Fund (Z.G.), and NSF (H.B.G.).Additional details
- Eprint ID
- 76580
- DOI
- 10.1021/ja028216j
- Resolver ID
- CaltechAUTHORS:20170417-064908538
- Israel Science Foundation
- 368/00
- American Chemical Society Petroleum Research Fund
- NSF
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2017-04-17Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field